TEEIA

有機廢溶劑能源化與再利用

鼎堅綠能科技股份有限公司

以熱裂解技術為基礎的污染防治設備,獨家創新的技術有效處理有機廢溶劑與VOCs揮發性有機化合物

Solution Details

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本公司有機廢溶劑處理技術主要透過高溫,在獨特的反應機構中將有機組份裂解,並可依照客戶需求導入不同觸媒以調整產物組成。

簡介


有機廢溶劑普遍存在於化工、光電半導體等產業,目前較為成熟的處理方式有再利用的分離回收與破壞性的焚化,然而現有技術在處理成分較多樣的有機廢溶劑或含氨廢水時,程序較複雜或難度高,衍生的廢熱回收效益較低,甚至有燃燒不完全的潛在污染問題等。對此,本公司導入『裂解與再利用』概念,透過將複雜有機組份或氨分解為氣態可燃成分如甲烷、短碳鏈化合物、一氧化碳以及氫氣等,作為製程替代或發電燃料,以更潔淨的方式減少處理過程產生的污染,並從能源角度實現循環再利用,落實循環經濟概念。


 技術架構

系統主要包括兩項核心單元:


熱裂解單元


  1. 用途:在高溫下將進料中有機組份斷鏈成為小分子。
  2. 效果:產出甲烷、短碳鏈化合物、一氧化碳以及氫氣等可燃成分,冷凝水COD符合排放標準。
  3. 其他重要技術特徵,加熱方式:天然氣/液化石油氣燃燒機供熱
  4. 注意事項:廢溶劑中含有硫化物、鹵素、金屬離子等成分,需評估導入前處理程序之需求,以減少對系統硬體壽命之影響。


熱回收單元

  1. 用途:回收製程中廢熱以減少操作能耗(燃料使用量)。
  2. 效果:將煙氣排放溫度降至約100℃左右。
  3. 其他重要技術特徵,加熱方式:天然氣/液化石油氣燃燒機供熱


運作方式


  • 熱裂解:啟動設備至設定溫度後,依設計入料速率進料,待平衡後於出口可取得可燃氣,並排放低COD冷凝水。
  • 後端應用:視需求設置應用設備。
  • 產製蒸氣:鍋爐
  • 發電:燃氣發電機、燃料電池(需視燃料電池種類先進行純化)
  • 製備高純度氣體:可導入氣體純化設備取得所需高純度氣體


主要規格


  • 單一模組處理量(噸/月):10 ~ 350 (註)
  • 以天然氣/液化石油氣供熱,另可依需求改用電力供熱
  • 細部設計需依照實際客戶條件而定

註:以COD=400,000為基準


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